Product ID:C-536, PRIMECOAT CURING AGENT
MSDS Date:01/20/1992
FSC:8010
NIIN:00N030326
MSDS Number: BNMVP

ADVANCE PROCESS SUPPLY

400 NORTH NOBLE
CHICAGO, IL 60622-6383
US

Emergency Phone: 312-942-8577

Info Phone: 312-829-1400

Cage: 29431

ADVANCE PROCESS SUPPLY CO.

CHICAGO, IL 60622-6383 US

Telephone: 312-942-8504

Cage: 29431

POLYMETHYLENEPOLYPHENYL ISOCYANATE; (POLYMERIC

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 100%

STAIN FOR EVIDENCE OF CORNEAL

RTECS: 9999999ZZ

PREPARATION FREQUENTLY.WORKPLACE VAPS HAVE PRDCED

RTECS: 9999999ZZ

THIS COMPOUND IS A KNOWN SKIN SENSITIZER. TREAT

RTECS: 9999999ZZ

TREAT

RTECS: 9999999ZZ

IS CONTRADICTED BECAUSE OF THE IRRITATING NATURE OF

RTECS: 9999999ZZ

SENSITIZER. TREATMENT IS ESSENTIALLY SYMPTOMATIC. AN

RTECS: 9999999ZZ

REACTION SHOULD BE REMOVED FROM EXPOSURE TO ANY

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CAUSES IRRIT. IF LEFT UNTREATED,
MAY CAUSE REVERSIBLE CORNEAL DAM. SKIN: CAUSES IRRIT. PRLNGD CONT
MAY CAUSE BLISTERING & ALLERGIC SENSIT. SENSITIZED INDIVIDUALS MAY
REACT TO VERY SM EXPOS. INHA L: VAP/MIST CAUSE IRRIT OF MUC MEMB IN
NOSE & THROAT & MAY CAUSE PERM LUNG DAM. SENSITIZED PERS MAY (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:HAVE AN ASTHMA ATTACK OR CHEMICAL
PNEUMONIA. PERSONS PREVIOUSLY SENSITIZED BY REPEATED
OVEREXPOSURE/SINGLE LARGE DOSE MAY EXPERIENCE AN ASTHMA ATTACK W/AN
EXPOSURE WELL BELOW TLV. INGEST: CAN CAUSE IRRITATION AND
CORROSION OF THE GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:ASTHMA, BRONCHITIS, EMPHYSEMA,
BRONCHIAL ALLERGIES, SKIN ALLERGIES, ECZEMA.

First Aid:EYES:IMMED FLUSH W/LG AMTS OF WATER FOR A LST 15 MIN,
OCCASIONALLY HOLDING LIDS OPEN.GET MED ATTN. SKIN:WASH THORO W/
SOAP & WATER. REMOVE CONTAMD CLOTHES. LAUNDER/CLEAN BEFORE REUSE.
IF SYMPS PERSIST /ARE SEV, GET MED ATTN. INHAL:REMOVE FROM EXPOS.
IF BRTHG IS DFCLT, ADMIN O2/ARTF RESP AS NEEDED & GET MED ATTN. IF
DELAYED REACTION OCCURS, GET IMMED MED ATTN. IF DELAYED REACTION
OCCURS, (SUPP DATA

Flash Point Method:PMCC
Flash Point:390F,199C
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HIGH EXPANSION
CHEMICAL FOAM, WATER SPRAY (FOR LARGE FIRES).
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL CONTAINERS.
Unusual Fire/Explosion Hazard:DURING FIRE, TOX MDI FUMES & OTHER HIGHLY
TOX GASES MAY BE GENERATED.AT TEMPS >400F, MDI MAY POLYMERIZE,
BUILD UP PRESS & RUPTURE CNTNRS.EMPTY CNTNRS(SUPP DATA)

Spill Release Procedures:ABSORB W/SAWDUST/OTHER SUITABLE ABSORBANT,
SHOVEL INTO UNSEALED CNTNRS & STORE OUTSIDE UNTIL MATL CAN BE
DISPOS OF. DECONTAM SPILL AREA W/MOISTURE OF 20% NONIONIC
DETERGENT-80% WATER/3-8% CONCENTRATED AMMONIA-2% DETERGENT-90%
WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE ONLY WITH ADEQUATE VENTILATION.
Other Precautions:DO NOT BREATHE DUST, MIST, OR VAPOR. AVOID CONTACT
WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED OR REPEATED CONTACT
WITH THE SKIN.

Respiratory Protection:USE A NIOSH/MSHA APPROVED SUPPLIED AIR
RESPIRATOR IF TLV MAY BE EXCEEDED.
Ventilation:PROVIDE ADEQUATE VENTILATION TO PREVENT EXCEEDING TLV. USE
LOCAL EXHAUST IF NECESSARY.
Protective Gloves:CHEM RESIST( NEOPRENE/NITRILE RUB)GLOVES
Eye Protection:CHEM WORK GOG & FULL LGTH FSHLD .
Other Protective Equipment:SAFETY SHOWER, EYEWASH STATION, IMPERVIOUS
CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT WEAR
CONTACT LENSES.
Supplemental Safety and Health
VP: <0.00005 @ 25C. SOL IN H2O:REACTS SLOWLY W/WATER TO LIBERATE CO2
GAS. EXPLO HAZ:COULD IGNITE EXPLOSIVELY IF HEATED. FIRST AID PROC:
GET IMMED MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF ALERT, GIVE 8
TO 16 OZ OF WATER OR MILK. IF MORE THAN A FEW DROPS WERE SWALLOWED,
GET MED ATTN. (ING 2)

HCC:T4
Boiling Pt:B.P. Text:406F,208C
Melt/Freeze Pt:M.P/F.P Text:<32F,<0C
Vapor Pres:SUPP DATA
Vapor Density:8.5
Spec Gravity:1.24 (H2O=1)
Solubility in Water:SUPP DATA
Appearance and Odor:DARK BROWN LIQUID, SLIGHTLY MUSTY ODOR
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:NO
WATER, AMINES, STRONG BASES, ALCOHOLS.
Stability Condition to Avoid:ELEVATED TEMPERATURES, FIRE, MOISTURE.
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
TRACES OF HCN, MDI.
Conditions to Avoid Polymerization:CONTACT WITH MOISTURE, HIGH
TEMPERATURES.

Waste Disposal Methods:DISPOSE OF IN A LICENSED TSD FACILITY I/A/W ALL
APPLICABLE LOCAL STATE AND FEDERAL REGULATIONS, PREFERRABLY BY
INCINERATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.